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Sand Hill venture firm Kleiner Perkins Caulfield Byers is taking social networking seriously. At least, that's the implication of its most recent hire: KPCB has added former Accel associate Chi-Hua Chien to its stable of general partners, according to an email sent yesterday by Chien. While at Accel, Chien worked on its Facebook investment and, we hear, was instrumental in fbFund, which distributed seed funding to companies focusing on creating applications for the Facebook platform. Prior to Accel, Chien was involved in corporate development during the early days of search giant Google.